Ceramics International
2018
Fabrication of highly-doped Nd3+:YAG transparent ceramics by reactive SPS
Авторы:
D.Yu.Kosyanov, R.P.Yavetskiy, A.V.Tolmachev, A.A.Vornovskikh, A.V.Pogodae, E.A.Gridasov, O.O. Shichalin, T.A. Kaidalov, V.G. Kuryavyi

Abstract. 4 at% Nd3+:YAG transparent ceramics have been prepared by reactive spark plasma sintering (SPS) in the 1200-1500°C temperature range. Microstructure, phase composition, optical and physico-mechanical properties of the obtained samples have been studied. Rapid heating of oxide powder system under pressure has been shown to provide single-phase garnet ceramics at 1350-1500°C in 5 minutes. Accelerated kinetics of YAM→YAP→YAG phase transformations under SPS conditions make sintering faster by an order of magnitude as compared to conventional routes. 4 at% Nd3+:YAG ceramics obtained at 1350°C under 30 MPa pressure in 5 minutes possesses mean grain size of 520 nm, microhardness of 13.7 MPa, and in-line optical transmittance coefficient of 70% in the visible wavelength range (for sample thickness of 1 mm).

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