Abstract Here we present a prospective method of sol-gel synthesis of highly porous wollastonite ceramic powders with controlled macroporous structure (mean pore size ~ 160 nm) and immobilized gold nanoparticles (particle size is less than 50 nm). The method's distinction is based on using the colloidal template (micelles of ''core-shell'' polymer latex) both as a poreforming agent and as nanoreactors for nanoparticle synthesis in the system wollastonite/AuNPs. We revealed the impact of template thermal removal on the morphology of nanostructured wollastonite. We also optimized thermal treatment to obtain defect-free macroporous calcium silicates. Template functionalization by size stabilized gold nanoparticles with their following immobilization into the porous volume of synthesized wollastonite has been described. Besides, an original nonstandard method of combined sol-gel (template) synthesis and spark plasma sintering (SPS) is suggested to obtain the wollastonite ceramic compounds with bimodal pore size distribution (100-500 nm and not less than 1 µm), high mechanical strength (compressive strength limit ~ 120 MPa) and containing immobilized Au-NPs. Peculiarities of biporous silicate framework formation has been studied using two types of poreforming agents (templates) of 2 various origin, shape and size, introduced during different stages of sol-gel and SPS processes. These templates are organoelemental polymer latex of “core-shell” type and nonorganic carbon filler. Developed approaches are innovative and provide to make new materials with unique characteristics and functional properties as bone-like structure, mechanical stability, antibacterial and anti-inflammatory effects and etc. The materials meet all the biomaterials requirements and are in high demand by modern medicine.

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